Flame Retardants Standards  
   
205 PBDEs Congeners Bromobiphenyl Congeners
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PBDE Mixtures
(EPA Method 524, 1614, ISO/DIS 22032)		 Bromophenols and Bromoanisoles
HBCD Isomers
60 PBCDE Metabolites
Hydroxy and Methoxy PBDEs		 Industrial Flame Retardants
Tech Grade PBDEs
30 Fluorinated PBDE (ISTD)
Alternatives for isotopically labeled materials		 Other Bromine Containing FRs
Chlorine Containing FRs
New Mixed Bromo/Chloro Hydroxylated Diphenyl Ethers New Organophosphates
 
   
  2011 Update
   
Polybromodiphenyl Ethers (PBDEs) 205 Congeners
       
50 µg/mL in Isooctane Cat. No. 50 µg/mL in Isooctane Cat. No.
2-Bromodiphenyl ether BDE-001S 2,3,3',4,4'-Pentabromodiphenyl ether BDE-105S
3-Bromodiphenyl ether BDE-002S 2,3,3',4,5-Pentabromodiphenyl ether BDE-106S
4-Bromodiphenyl ether BDE-003S 2,3,3',4',5-Pentabromodiphenyl ether BDE-107S
    2,3,3',4,5'-Pentabromodiphenyl ether BDE-108S
2,2'-Dibromodiphenyl ether BDE-004S 2,3,3',4,6-Pentabromodiphenyl ether BDE-109S
2,3-Dibromodiphenyl ether BDE-005S 2,3,3’,4’,6-Pentabromodiphenyl ether BDE-110S
2,3'-Dibromodiphenyl ether BDE-006S 2,3,3',5,5'-Pentabromodiphenyl ether BDE-111S
2,4-Dibromodiphenyl ether BDE-007S 2,3,3',5,6-Pentabromodiphenyl ether BDE-112S
2,4'-Dibromodiphenyl ether BDE-008S 2,3,3’,5’,6-Pentabromodiphenyl ether BDE-113S
2,5-Dibromodiphenyl ether BDE-009S 2,3,4,4',5-Pentabromodiphenyl ether BDE-114S
2,6-Dibromodiphenyl ether BDE-010S 2,3,4,4',6-Pentabromodiphenyl ether BDE-115S
3,3'-Dibromodiphenyl ether BDE-011S 2,3,4,5,6-Pentabromodiphenyl ether BDE-116S
3,4-Dibromodiphenyl ether BDE-012S 2,3,4,5,6-Pentabromodiphenyl ether BDE-117S
3,4'-Dibromodiphenyl ether BDE-013S 2,3',4,4',5-Pentabromodiphenyl ether BDE-118S
3,5-Dibromodiphenyl ether BDE-014S 2,3',4,4',6-Pentabromodiphenyl ether BDE-119S
4,4'-Dibromodiphenyl ether BDE-015S 2,3',4,5,5'-Pentabromodiphenyl ether BDE-120S
    2,3',4,5',6-Pentabromodiphenyl ether BDE-121S
2,2',3-Tribromodiphenyl ether BDE-016S 2',3,3',4,5-Pentabromodiphenyl ether BDE-122S
2,2',4-Tribromodiphenyl ether BDE-017S 2',3,4,4',5-Pentabromodiphenyl ether BDE-123S
2,2',5-Tribromodiphenyl ether BDE-018S 2',3,4,5,5'-Pentabromodiphenyl ether BDE-124S
2,2',6-Tribromodiphenyl ether BDE-019S 2',3,4,5,6'-Pentabromodiphenyl ether BDE-125S
2,3,3'-Tribromodiphenyl ether BDE-020S 3,3',4,4',5'-Pentabromodiphenyl ether BDE-126S
2,3,4-Tribromodiphenyl ether BDE-021S 3,3',4,5,5'-Pentabromodiphenyl ether BDE-127S
2,3',4'-Tribromodiphenyl ether BDE-022S    
2,3,5-Tribromodiphenyl ether BDE-023S 2,2',3,3',4,4'-Hexabromodiphenyl ether BDE-128S
2,3,6-Tribromodiphenyl ether BDE-024S 2,2',3,3',4,5-Hexabromodiphenyl ether BDE-129S
2,3',4-Tribromodiphenyl ether BDE-025S 2,2',3,3',4,5'-Hexabromodiphenyl ether BDE-130S
2,3',5-Tribromodiphenyl ether BDE-026S 2,2',3,3',4,6-Hexabromodiphenyl ether BDE-131S
2,3',6-Tribromodiphenyl ether BDE-027S 2,2’,3,3’,4,6’-Hexabromodiphenyl ether BDE-132S
2,4,4'-Tribromodiphenyl ether BDE-028S 2,2',3,3’,5,5'-Hexabromodiphenyl ether BDE-133S
2,4,5-Tribromodiphenyl ether BDE-029S 2,2',3,3’,5,6-Hexabromodiphenyl ether BDE-134S
2,4,6-Tribromodiphenyl ether BDE-030S 2,2’,3,3’,5,6’-Hexabromodiphenyl ether BDE-135S
2,4',5-Tribromodiphenyl ether BDE-031S 2,2',3,3',6,6'-Hexabromodiphenyl ether BDE-136S
2,4',6-Tribromodiphenyl ether BDE-032S 2,2',3,4,4',5-Hexabromodiphenyl ether BDE-137S
2',3,4-Tribromodiphenyl ether BDE-033S 2,2',3,4,4',5'-Hexabromodiphenyl ether BDE-138S
2',3,5-Tribromodiphenyl ether BDE-034S 2,2',3,4,4',6-Hexabromodiphenyl ether BDE-139S
3,3',4-Tribromodiphenyl ether BDE-035S 2,2',3,4,4',6'-Hexabromodiphenyl ether BDE-140S
3,3',5-Tribromodiphenyl ether BDE-036S 2,2',3,4,5,5'-Hexabromodiphenyl ether BDE-141S
3,4,4'-Tribromodiphenyl ether BDE-037S 2,2',3,4,5,6-Hexabromodiphenyl ether BDE-142S
3,4,5-Tribromodiphenyl ether BDE-038S 2,2',3,4,5,6'-Hexabromodiphenyl ether BDE-143S
3,4',5-Tribromodiphenyl ether BDE-039S 2,2',3,4,5',6-Hexabromodiphenyl ether BDE-144S
    2,2',3,4,6,6'-Hexabromodiphenyl ether BDE-145S
2,2',3,3'-Tetrabromodiphenyl ether BDE-040S 2,2',3,4,5',6-Hexabromodiphenyl ether BDE-146S
2,2',3,4-Tetrabromodiphenyl ether BDE-041S 2,2',3,4',5,6-Hexabromodiphenyl ether BDE-147S
2,2',3,4'-Tetrabromodiphenyl ether BDE-042S 2,2',3,4,5',6-Hexabromodiphenyl ether BDE-148S
2,2',3,5-Tetrabromodiphenyl ether BDE-043S 2,2’,3,4’,5’,6-Hexabromodiphenyl ether BDE-149S
2,2',3,5'-Tetrabromodiphenyl ether BDE-044S 2,2',3,4',6,6'-Hexabromodiphenyl ether BDE-150S
2,2’,3,6-Tetrabromodiphenyl ether BDE-045S 2,2',3,5,5',6-Hexabromodiphenyl ether BDE-151S
2,2',3,6'-Tetrabromodiphenyl ether BDE-046S 2,2',3,5,6,6'-Hexabromodiphenyl ether BDE-152S
2,2',4,4'-Tetrabromodiphenyl ether BDE-047S 2,2',4,4',5,5'-Hexabromodiphenyl ether BDE-153S
2,2',4,5-Tetrabromodiphenyl ether BDE-048S 2,2',4,4',5,6'-Hexabromodiphenyl ether BDE-154S
2,2',4,5'-Tetrabromodiphenyl ether BDE-049S 2,2',4,4',6,6'-Hexabromodiphenyl ether BDE-155S
2,2',4,6-Tetrabromodiphenyl ether BDE-050S 2,3,3',4,4',5-Hexabromodiphenyl ether BDE-156S
2,2',4,6'-Tetrabromodiphenyl ether BDE-051S 2,3,3',4,4',5'-Hexabromodiphenyl ether BDE-157S
2,2',5,5'-Tetrabromodiphenyl ether BDE-052S 2,3,3',4,4',6-Hexabromodiphenyl ether BDE-158S
2,2',5,6'-Tetrabromodiphenyl ether BDE-053S 2,3,3',4,5,5'-Hexabromodiphenyl ether BDE-159S
2,2',6,6'-Tetrabromodiphenyl ether BDE-054S 2,3,3',4,5,6-Hexabromodiphenyl ether BDE-160S
2,3,3',4-Tetrabromodiphenyl ether BDE-055S 2,3,3',4,5',6-Hexabromodiphenyl ether BDE-161S
2,3,3',4'-Tetrabromodiphenyl ether BDE-056S 2,3,3',4',5,5'-Hexabromodiphenyl ether BDE-162S
2,3,3',5-Tetrabromodiphenyl ether BDE-057S 2,3,3',4',5,6-Hexabromodiphenyl ether BDE-163S
2,3,3',5'-Tetrabromodiphenyl ether BDE-058S 2,3,3’,4’,5’,6-Hexabromodiphenyl ether BDE-164S
2,3,3’,6-Tetrabromodiphenyl ether BDE-059S 2,3,3',5,5',6-Hexabromodiphenyl ether BDE-165S
2,3,4,4'-Tetrabromodiphenyl ether BDE-060S 2,3,4,4',5,6-Hexabromodiphenyl ether BDE-166S
2,3,4,5-Tetrabromodiphenyl ether BDE-061S 2,3',4,4',5,5'-Hexabromodiphenyl ether BDE-167S
2,3,4,6-Tetrabromodiphenyl ether BDE-062S 2,3',4,4',5',6-Hexabromodiphenyl ether BDE-168S
2,3,4',5-Tetrabromodiphenyl ether BDE-063S 3,3',4,4',5,5'-Hexabromodiphenyl ether BDE-169S
2,3,4’,6-Tetrabromodiphenyl ether BDE-064S    
2,3,5,6-Tetrabromodiphenyl ether BDE-065S 2,2',3,3',4,4',5-Heptabromodiphenyl ether BDE-170S
2,3',4,4'-Tetrabromodiphenyl ether BDE-066S 2,2',3,3',4,4',6-Heptabromodiphenyl ether BDE-171S
2,3',4,5-Tetrabromodiphenyl ether BDE-067S 2,2',3,3',4,5,5'-Heptabromodiphenyl ether BDE-172S
2,3',4,5'-Tetrabromodiphenyl ether BDE-068S 2,2',3,3',4,5,6-Heptabromodiphenyl ether BDE-173S
2,3',4,6-Tetrabromodiphenyl ether BDE-069S 2,2',3,3',4,5',6-Heptabromodiphenyl ether BDE-175S
2,3',4',5-Tetrabromodiphenyl ether BDE-070S 2,2',3,3',4,6,6'-Heptabromodiphenyl ether BDE-176S
2,3',4',6-Tetrabromodiphenyl ether BDE-071S 2,2',3,3',4',5,6-Heptabromodiphenyl ether BDE-177S
2,3',5,5'-Tetrabromodiphenyl ether BDE-072S 2,2',3,3',5,5',6-Heptabromodiphenyl ether BDE-178S
2,3',5',6-Tetrabromodiphenyl ether BDE-073S 2,2',3,3',4,5',6-Heptabromodiphenyl ether BDE-180S
2,4,4',5-Tetrabromodiphenyl ether BDE-074S 2,2',3,4,4',5,6-Heptabromodiphenyl ether BDE-181S
2,4,4',6-Tetrabromodiphenyl ether BDE-075S 2,2',3,4,4',5,6'-Heptabromodiphenyl ether BDE-182S
2',3,4,5-Tetrabromodiphenyl ether BDE-076S 2,2',3,4,4',5',6-Heptabromodiphenyl ether BDE-183S
3,3',4,4'-Tetrabromodiphenyl ether BDE-077S 2,2',3,4,4',6,6'-Heptabromodiphenyl ether BDE-184S
3,3',4,5-Tetrabromodiphenyl ether BDE-078S 2,2',3,4,5,5',6-Heptabromodiphenyl ether BDE-185S
3,3',4,5'-Tetrabromodiphenyl ether BDE-079S 2,2',3,4,5,6,6'-Heptabromodiphenyl ether BDE-186S
3,3',5,5'-Tetrabromodiphenyl ether BDE-080S 2,2’,3,4’,5,5’,6-Heptabromodiphenyl ether BDE-187S
3',4,4',5-Tetrabromodiphenyl ether BDE-081S 2,2',3,4',5,6,6'-Heptabromodiphenyl ether BDE-188S
    2,3,3',4,4',5,5'-Heptabromodiphenyl ether BDE-189S
2,2',3,3',4-Pentabromodiphenyl ether BDE-082S 2,3,3',4,4',5,6-Heptabromodiphenyl ether BDE-190S
2,2',3,3',5-Pentabromodiphenyl ether BDE-083S 2,3,3',4,4',5',6-Heptabromodiphenyl ether BDE-191S
2,2’,3,3’,6-Pentabromodiphenyl ether BDE-084S 2,3,3',4,5,5',6-Heptabromodiphenyl ether BDE-192S
2,2',3,4,4'-Pentabromodiphenyl ether BDE-085S 2,3,3',4',5,5',6-Heptabromodiphenyl ether BDE-193S
2,2',3,4,5-Pentabromodiphenyl ether BDE-086S    
2,2',3,4,5'-Pentabromodiphenyl ether BDE-087S 2,2',3,3',4,4',5,5'-Octabromodiphenyl ether BDE-194S
2,2',3,4,6-Pentabromodiphenyl ether BDE-088S 2,2',3,3',4,4',5,6-Octabromodiphenyl ether BDE-195S
2,2',3,4,6'-Pentabromodiphenyl ether BDE-089S 2,2',3,3',4,4',5,6'-Octabromodiphenyl ether BDE-196S
2,2',3,4',5-Pentabromodiphenyl ether BDE-090S 2,2',3,3',4,4',6,6'-Octabromodiphenyl ether BDE-197S
2,2’,3,4’,6-Pentabromodiphenyl ether BDE-091S 2,2',3,3',4,5,5',6-Octabromodiphenyl ether BDE-198S
2,2',3,5,5'-Pentabromodiphenyl ether BDE-092S 2,2',3,3',4,5',6,6'-Octabromodiphenyl ether NEW BDE-200S
2,2',3,5,6-Pentabromodiphenyl ether BDE-093S 2,2',3,3',4,5',6,6'-Octabromodiphenyl ether BDE-201S
2,2',3,5,6'-Pentabromodiphenyl ether BDE-094S 2,2',3,3',5,5',6,6'-Octabromodiphenyl ether BDE-202S
2,2’,3,5’,6-Pentabromodiphenyl ether BDE-095S 2,2',3,4,4',5,5',6-Octabromodiphenyl ether BDE-203S
2,2’,3,6,6’-Pentabromodiphenyl ether BDE-096S 2,2',3,4,4',5,6,6'-Octabromodiphenyl ether BDE-204S
2,2',3',4,5-Pentabromodiphenyl ether BDE-097S 2,3,3',4,4',5,5',6-Octabromodiphenyl ether BDE-205S
2,2',3',4,6-Pentabromodiphenyl ether BDE-098S 2,2',3,3',4,4',5,5',6-Nonabromodiphenyl ether BDE-206S
2,2',4,4',5-Pentabromodiphenyl ether BDE-099S 2,2',3,3',4,4',5,6,6'-Nonabromodiphenyl ether BDE-207S-R1
2,2',4,4',6-Pentabromodiphenyl ether BDE-100S 2,2',3,3',4,5,5',6,6'-Nonabromodiphenyl ether BDE-208S
2,2',4,5,5'-Pentabromodiphenyl ether BDE-101S    
2,2',4,5,6'-Pentabromodiphenyl ether BDE-102S Decabromodiphenyl ether BDE-209S
2,2',4,5',6-Pentabromodiphenyl ether BDE-103S  
2,2',4,6,6'-Pentabromodiphenyl ether BDE-104S    
       
Technical Grade PBDEs
Compound    
Qty./Conc. Matrix Cat. No.
Bromkal DE-70-5 (Tech grade) 50 µg/mL Isooctane BDE-705
Bromkal DE-71 (Tech grade) 50 µg/mL Isooctane BDE-710
Bromkal DE-73-6 (Tech grade) 50 µg/mL Isooctane BDE-736
Bromkal DE-79-8 (Tech grade) 50 µg/mL Isooctane BDE-798
FR-300BA (Deca) 10 mg NEAT FRS-009N
100 µg/mL Toluene FRS-009S
         
PBDE Congeners Common to Technical Mixtures (Bromkal™)   DE-71 (Pentas) Great Lakes
BDE-BROMKAL   BDE-710-GL
10 µg/mL each in Isooctane   50 µg/mL in Isooctane
     
2,4,4’-Tribromodiphenyl ether (#28)   Bromkal DE-71
2,2’,4,4’-Tetrabromodiphenyl ether (#47)    
2,2’,4,4’,5-Pentabromodiphenyl ether (#99)   DE-79 (Octas) Great Lakes
2,2’,4,4’,6-Pentabromodiphenyl ether (#100)   BDE-798-GL
2,2’,4,4’,5,5'-Hexabromodiphenyl ether (#153)   50 µg/mL in Isooctane
2,2’,4,4’,5,6'-Hexabromodiphenyl ether (#154)        
    Bromkal DE-79 (Great Lakes)
         
   
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PBDE Mixtures
 
PBDE Most Common in US Environment PBDE Congeners Common in California Environment
BDE-USE BDE-CAE-1
10 µg/mL each in Isooctane 10 µg/mL each in Isooctane
   
2,2',4,4'-Tetrabromodiphenyl ether (#28) 2,4,4’-Tribromodiphenyl ether (#28)
2,2',4,4',5-Pentabromodiphenyl ether (#99) 2',3,4-Tribromodiphenyl ether (#33)
2,2',4,4',6-Pentabromodiphenyl ether (#100) 2,2’,4,4’-Tetrabromodiphenyl ether (#47)
2,2',4,4',5,5'-Hexabromodiphenyl ether (#153) 2,2’,4,4’,5-Pentabromodiphenyl ether (#99)
2,2',4,4',5,6'-Hexabromodiphenyl ether (#154) 2,2’,4,4’,6-Pentabromodiphenyl ether (#100)
  2,2’,4,4’,5,5'-Hexabromodiphenyl ether (#153)
PBDEs - Columbia River Study 2,2’,4,4’,5,6'-Hexabromodiphenyl ether (#154)
BDE-CR  
10 µg/mL each in Isooctane  
  PBDEs - Lake Michigan Study
4,4’-Dibromodiphenyl ether (#15) BDE-LMS
2,4,4’-Tribromodiphenyl ether (#28) 10 µg/mL each in Isooctane
2’,3,4-Tribromodiphenyl ether (#33)  
2,2’,4,4’-Tetrabromodiphenyl ether (#47) 2,4,4'-Tribromodiphenyl ether (#28)
2,2’,4,5’-Tetrabromodiphenyl ether (#49) 2,2',4,4'-Tetrabromodiphenyl ether (#47)
2,3’,4,4’-Tetrabromodiphenyl ether (#66) 2,3',4,4'-Tetrabromodiphenyl ether (#66)
2,4,4’,6-Tetrabromodiphenyl ether (#75) 2,2',3,4,4'-Pentabromodiphenyl ether (#85)
2,2’,4,4’,5-Pentabromodiphenyl ether (#99) 2,2',4,4',5-Pentabromodiphenyl ether (#99)
2,2’,4,4’,6-Pentabromodiphenyl ether (#100) 2,2',4,4',6-Pentabromodiphenyl ether (#100)
2,2’,4,4’,5,5’-Hexabromodiphenyl ether (#153) 2,2',3,4,4',5'-Hexabromodiphenyl ether (#138)
2,2’,4,4’,5,6’-Hexabromodiphenyl ether (#154) 2,2',4,4',5,5'-Hexabromodiphenyl ether (#153)
2,2’,4,4’,6,6’-Hexabromodiphenyl ether (#155) 2,2',4,4',5,6'-Hexabromodiphenyl ether (#154)
   
California Method 750-M Standard EPA Method 527 - PBDE Standard New
BDE-CALEWS M-527-BDE
10 µg/mL each in Isooctane 50 µg/mL each in Isooctane:Ethyl acetate (8:2)
   
2,2’,4-Tribromodiphenyl ether (#17) 2,2’,4,4’-Tetrabromodiphenyl ether
2,4,4’-Tribromodiphenyl ether (#28) 2,2’,4,4’,6-Pentabromodiphenyl ether
2,2’,4,4’-Tetrabromodiphenyl ether (#47) 2,2’,4,4’,5-Pentabromodiphenyl ether
2,3’,4,4’-Tetrabromodiphenyl ether (#66) 2,2’,4,4’,5,5'-Hexabromodiphenyl ether
2,3’,4’,6-Tetrabromodiphenyl ether (#71) 2,2',4,4',5,5'-Hexabromobiphenyl
2,2’,4,4’,5-Pentabromodiphenyl ether (#99)  
2,2’,4,4’,6-Pentabromodiphenyl ether (#100)  
2,2’,3,4,4’,5’-Hexabromodiphenyl ether (#138)  
2,2',4,4',5,5’-Hexabromodiphenyl ether (#153)  
2,2’,4,4’,5,6’-Hexabromodiphenyl ether (#154)  
2,2’,3,4,4',5',6-Heptabromodiphenyl ether (#183)  
2,2’,3,3’,4,4’,5,5’,6,6’-Decabromodiphenyl ether (#209)  
2,2’,6,6’-Tetrabromobisphenol A  
   
ISO/DIS 22032 Calibration Curve Set
               
ISO/DIS-22032-SET             7 x 1 mL
At stated conc. (ng/mL) in Isooctane             8 comps. each
(BZ#)              
ISO/DIS-22032 01 02 03 04 05 06 07
2,2’,4,4’-Tetrabromodiphenyl ether (#47) 5 12.5 25 50 100 150 250
2,2’,4,4’,5-Pentabromodiphenyl ether (#99) 5 12.5 25 50 100 150 250
2,2’,4,4’,6-Pentabromodiphenyl ether (#100) 5 12.5 25 50 100 150 250
2,2’,4,4’,5,5'-Hexabromodiphenyl ether (#153) 5 12.5 25 50 100 150 250
2,2’,4,4’,5,6'-Hexabromodiphenyl ether (#154) 5 12.5 25 50 100 150 250
2,2',3,4,4',5',6-Heptabromodiphenyl ether (#183) 5 12.5 25 50 100 150 250
2,3,3',4,4',5,5',6-Octabromodiphenyl ether (#205) 5 12.5 25 50 100 150 250
2,2',3,3',4,4',5,5',6,6'-Decabromodiphenyl ether (#209) 25 50 100 200 500 700 1000
               
ISO/DIS-22032 Internal Standard for BDE-47, 99 & 100              
ISO22032-IS-1-5ML 1 x 5 mL            
ISO22032-IS-1-10ML 1 x 10 mL            
100 ng/mL in Isooctane              
               
3,3’,4,4’-Tetrabromodiphenyl ether (#47)              
               
ISO/DIS-22032 Internal Standard for BDE-153, 154 & 183              
ISO22032-IS-2-5ML 1 x 5 mL            
ISO22032-IS-2-10ML 1 x 10 mL            
100 ng/mL in Isooctane              
               
2,2’,3,4,4’,5,6-Heptabromodiphenyl ether(#181)              
               
Method 1614 Polybrominated Diphenyl Ethers (PBDEs) Mixtures
 
Mixture of Commonly Occurring PBDE Congeners for Precision and Recovery
BDE-COC 1 x 1 mL  
At stated conc. (µg/mL) in Isooctane 14 comps.  
(BZ#) µg/mL  
2,2’,4,-Tribromodiphenyl ether (#17) 5  
2,4,4’-Tribromodiphenyl ether (#28) 5  
2,2’,4,4’-Tetrabromodiphenyl ether (#47) 5  
2,3’,4,4’-Tetrabromodiphenyl ether (#66) 5  
2,3’,4’,6-Tetrabromodiphenyl ether (#71) 5  
2,2’,3,4,4’-Pentabromodiphenyl ether (#85) 5  
2,2’,4,4’,5-Pentabromodiphenyl ether (#99) 5  
2,2’,4,4’,6-Pentabromodiphenyl ether (#100) 5  
2,2’,3,4,4’,5’-Hexabromodiphenyl ether (#138) 5  
2,2’,4,4’,5,5’-Hexabromodiphenyl ether (#153) 5  
2,2’,4,4’,5,6’-Hexabromodiphenyl ether (#154) 5  
2,2',3,4,4',5',6-Heptabromodiphenyl ether (#183) 5  
2,3,3’,4,4’,5,6-Heptabromodiphenyl ether (#190) 5  
Decabromodiphenyl ether (#209) 25  
     
Mixture of PBDEs Standard Solution for Accuracy & Precision
At stated conc. in Isooctane   39 comps.
  BDE-AAP-A BDE-AAP-A-15X
Component (BZ#) 1 x 1 mL 1 x 1 mL
  ng/mL µg/mL
2-Bromodiphenyl ether (#1) 100 1.5
3-Bromodiphenyl ether (#2) 100 1.5
4-Bromodiphenyl ether (#3) 100 1.5
2,4-Dibromodiphenyl ether (#7) 100 1.5
2,4’-Dibromodiphenyl ether (#8) 100 1.5
2,6-Dibromodiphenyl ether (#10) 100 1.5
3,3’-Dibromodiphenyl ether (#11) 100 1.5
3,4-Dibromodiphenyl ether (#12) 100 1.5
3,4’-Dibromodiphenyl ether (#13) 100 1.5
4,4’-Dibromodiphenyl ether (#15) 100 1.5
2,2’,4,-Tribromodiphenyl ether (#17) 100 1.5
2,3’,4-Tribromodiphenyl ether (#25) 100 1.5
2,4,4’-Tribromodiphenyl ether (#28) 100 1.5
2,4,6-Tribromodiphenyl ether (#30) 100 1.5
2,4’,6-Tribromodiphenyl ether (#32) 100 1.5
2’,3,4-Tribromodiphenyl ether (#33) 100 1.5
3,3’,4-Tribromodiphenyl ether (#35) 100 1.5
3,4,4’-Tribromodiphenyl ether (#37) 100 1.5
2,2’,4,4’-Tetrabromodiphenyl ether (#47) 100 1.5
2,2’,4,5’-Tetrabromodiphenyl ether (#49) 100 1.5
2,3’,4,4’-Tetrabromodiphenyl ether (#66) 100 1.5
2,3’,4’,6-Tetrabromodiphenyl ether (#71) 100 1.5
2,4,4’,6-Tetrabromodiphenyl ether (#75) 100 1.5
3,3’,4,4'-Tetrabromodiphenyl ether (#77) 100 1.5
2,2’,3,4,4’-Pentabromodiphenyl ether (#85) 150 2.25
2,2’,4,4’,5-Pentabromodiphenyl ether (#99) 150 2.25
2,2’,4,4’,6-Pentabromodiphenyl ether (#100) 150 2.25
2,3,4,5,6-Pentabromodiphenyl ether (#116) 150 2.25
2,3’,4,4’,5-Pentabromodiphenyl ether (#118) 150 2.25
2,3’,4,4’,6-Pentabromodiphenyl ether (#119) 150 2.25
3,3’,4,4’,5-Pentabromodiphenyl ether (#126) 150 2.25
2,2’,3,4,4’,5’-Hexabromodiphenyl ether (#138) 200 3
2,2’,4,4’,5,5’-Hexabromodiphenyl ether (#153) 200 3
2,2’,4,4’,5,6’-Hexabromodiphenyl ether (#154) 200 3
2,2’,4,4’,6,6’-Hexabromodiphenyl ether (#155) 200 3
2,3,4,4’,5,6-Hexabromodiphenyl ether (#166) 200 3
2,2’,3,4,4’,5,6-Heptabromodiphenyl ether (#181) 250 3.75
2,2',3,4,4',5',6-Heptabromodiphenyl ether (#183) 250 3.75
2,3,3’,4,4’,5,6-Heptabromodiphenyl ether (#190) 250 3.75
     
PBDE Congeners of Primary Interest  
BDE-CSM 1 x 1 mL  
At stated conc. in Isooctane (BZ#) 8 comps.  
  µg/mL  
2,4,4’-Tribromodiphenyl ether (#28) 20  
2,2’,4,4’-Tetrabromodiphenyl ether (#47) 20  
2,2’,4,4’,5-Pentabromodiphenyl ether (#99) 20  
2,2’,4,4’,6-Pentabromodiphenyl ether (#100) 20  
2,2’,4,4’,5,5’-Hexabromodiphenyl ether (#153) 20  
2,2’,4,4’,5,6’-Hexabromodiphenyl ether (#154) 20  
2,2',3,4,4’,5’,6-Heptabromodiphenyl ether (#183) 20  
Decabromodiphenyl ether (#209) 200  
     
PBDE Congeners of Primary Interest
Calibration Mix    
BDE-CM   1 x 1 mL
At stated conc. in Isooctane (BZ#)   8 comps.
Matrix Spiking Solution    
BDE-MS   1 x 1 mL
At stated conc. in Isooctane (BZ#)   8 comps.
  BDE-CM BDE-MS
  µg/mL ng/mL
2,4,4’-Tribromodiphenyl ether (#28) 2.5 1
2,2’,4,4’-Tetrabromodiphenyl ether (#47) 2.5 1
2,2’,4,4’,5-Pentabromodiphenyl ether (#99) 2.5 1
2,2’,4,4’,6-Pentabromodiphenyl ether (#100) 2.5 1
2,2’,4,4’,5,5’-Hexabromodiphenyl ether (#153) 2.5 1
2,2’,4,4’,5,6’-Hexabromodiphenyl ether (#154) 2.5 1
2,2’,3,4,4’,5’,6-Heptabromodiphenyl ether (#183) 2.5 1
Decabromodiphenyl ether (#209) 25 10
     
PBDEs in Method 1614    
BDE-EPA-SET 8 x 1 mL  
50 µg/mL each in Isooctane    
     
2,4,4’-Tribromodiphenyl ether    
2,2’,4,4’-Tetrabromodiphenyl ether    
2,2’,4,4’,5-Pentabromodiphenyl ether    
2,2’,4,4’,6-Pentabromodiphenyl ether    
2,2’,4,4’,5,5'-Hexabromodiphenyl ether    
2,2’,4,4’,5,6'-Hexabromodiphenyl ether    
2,2',3,4,4',5',6-Heptabromodiphenyl ether    
Decabromodiphenyl ether    
   
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PBDE Metabolites: Hydroxy and Methoxy PBDE Congeners
 

Hydroxylated and methoxylated PBDEs may be formed as metabolites of the widely used PBDE flame retardants. AccuStandard synthesizes authentic OH- and MeO-PBDE reference standards for analytical and toxicological studies.
Short Form Compound Cat. No. (1 mL)
Hydroxy    
2'-OH-BDE-003 2'-Hydroxy-4-monobromodiphenyl ether HBDE-1001S-CN
3'-OH-BDE-007 3'-Hydroxy-2,4-dibromodiphenyl ether HBDE-2001S-CN
2'-OH-BDE-007 2'-Hydroxy-2,4-dibromodiphenyl ether HBDE-2002S-CN-0.2X
4'-OH-BDE-017 4'-Hydroxy-2,2',4-tribromodiphenyl ether HBDE-3001S-CN
3'-OH-BDE-028 3'-Hydroxy-2,4,4'-tribromodiphenyl ether HBDE-3002S-CN
3'-OH-BDE-028 2'-Hydroxy-2,4,4'-tribromodiphenyl ether HBDE-3003S-CN
4-OH-BDE-042 4-Hydroxy-2,2',3,4'-tetrabromodiphenyl ether HBDE-4001S-CN-0.2X
4'-OH-BDE-049 4'-Hydroxy-2,2',4,5'-tetrabromodiphenyl ether HBDE-4002S-CN-0.2X
3-OH-BDE-047 3-Hydroxy-2,2',4,4'-tetrabromodiphenyl ether HBDE-4003S-CN
5-OH-BDE-047 5-Hydroxy-2,2',4,4'-tetrabromodiphenyl ether HBDE-4004S-CN
6-OH-BDE-047 6-Hydroxy-2,2',4,4'-tetrabromodiphenyl ether HBDE-4005S-CN-0.2X
HBDE-4005S-T-0.2X
2'-OH-BDE-068 2'-Hydroxy-2,3',4,5'-Tetrabromodiphenyl ether HBDE-4006S-CN-0.2X
HBDE-4006S-T-0.2X
HBDE-4006S-CN
HBDE-4006S-T
2’-OH-BDE-075 2’-Hydroxy-2,4,4’,6-tetrabromodiphenyl ether HBDE-4007S-CN-0.2X
4-OH-BDE-090 4-Hydroxy-2,2',3,4',5-pentabromodiphenyl ether HBDE-5001S-CN-0.2X
6-OH-BDE-085 6-Hydroxy-2,2',3,4,4'-pentabromodiphenyl ether HBDE-5002S-CN-0.2X
6-OH-BDE-087 6-Hydroxy-2,2',3,4,5'-pentabromodiphenyl ether HBDE-5003S-CN-0.2X
6-OH-BDE-082 6-Hydroxy-2,2',3,3',4-pentabromodiphenyl ether HBDE-5005S-CN-0.2X
6'-OH-BDE-099 6'-Hydroxy-2,2',4,4',5-pentabromodiphenyl ether HBDE-5006S-CN-0.2X
5'-OH-BDE-099 5'-Hydroxy-2,2',4,4',5-pentabromodiphenyl ether HBDE-5007S-CN-0.2X
3-OH-BDE-100 3-Hydroxy-2,2',4,4',6-pentabromodiphenyl ether HBDE-5008S-CN
4'-OH-BDE-101 4'-Hydroxy-2,2',4,5,5'-pentabromodiphenyl ether HBDE-5009S-CN
6-OH-BDE-157 6-Hydroxy-2,3,3',4,4',5'-hexabromodiphenyl ether HBDE-6001S-CN-0.2X
6-OH-BDE-140 6-Hydroxy-2,2',3,4,4',6'-hexabromodiphenyl ether HBDE-6002S-CN-0.2X
3'-OH-BDE-154 3'-Hydroxy-2,2',4,4',5,6'-hexabromodiphenyl ether HBDE-6003S-CN-0.2X
6-OH-BDE-137 6-Hydroxy-2,2',3,4,4',5-hexabromodiphenyl ether HBDE-6004S-CN-0.2X
4-OH-BDE-146 4-Hydroxy-2,2',3,4,5,5'-hexabromodiphenyl ether HBDE-6006S-CN-0.2X
4-OH-BDE-187 4-Hydroxy-2,2',3,4',5,5',6-hexabromodiphenyl ether HBDE-7001S-CN
6-OH-BDE-180 6-Hydroxy-2,2',3,4,4',5,5'-hexabromodiphenyl ether HBDE-7002S-CN
4-OH-BDE-188 4-Hydroxy-2,2',3,4',5,6,6'-hexabromodiphenyl ether HBDE-7003S-CN
6-OH-BDE-182 6-Hydroxy-2,2',3,4,4',5,6'-hexabromodiphenyl ether HBDE-7004S-CN-0.2X
4'-OH-BDE-201 4'-Hydroxy-2,2',3,3',4,5',6,6'-octabromodiphenyl ether HBDE-8001S-CN
     
Methoxy    
2'-MeO-BDE-003 2'-Methoxy-4-monobromodiphenyl ether MOBDE-1001S
3'-MeO-BDE-007 3'-Methoxy-2,4-dibromodiphenyl ether MOBDE-2001S
2'-MeO-BDE-007 2'-Methoxy-2,4-dibromodiphenyl ether MOBDE-2002S-0.2X
4'-MeO-BDE-017 4'-Methoxy-2,2',4-tribromodiphenyl ether MOBDE-3001S
3'-MeO-BDE-028 3'-Methoxy-2,4,4'-tribromodiphenyl ether MOBDE-3002S
2'-MeO-BDE-028 2'-Methoxy-2,4,4'-tribromodiphenyl ether MOBDE-3003S
4-MeO-BDE-042 4-Methoxy-2,2',3,4'-tetrabromodiphenyl ether MOBDE-4001S-0.2X
4'-MeO-BDE-049 4'-Methoxy-2,2',4,5'-tetrabromodiphenyl ether MOBDE-4002S-0.2X
3-MeO-BDE-047 3-Methoxy-2,2',4,4'-tetrabromodiphenyl ether MOBDE-4003S
5-MeO-BDE-047 5-Methoxy-2,2',4,4'-tetrabromodiphenyl ether MOBDE-4004S
6-MeO-BDE-047 6-Methoxy-2,2',4,4'-tetrabromodiphenyl ether MOBDE-4005S-0.2X
2'-MeO-BDE-068 2'-Methoxy-2,3',4,5'-tetrabromodiphenyl ether MOBDE-4006S-0.2X
2’-MeO-BDE-075 2’-Methoxy-2,4,4’,6-tetrabromodiphenyl ether MOBDE-4007S
4-MeO-BDE-090 4-Methoxy-2,2',3,4',5-pentabromodiphenyl ether MOBDE-5001S-0.2X
6-MeO-BDE-085 6-Methoxy-2,2',3,4,4'-pentabromodiphenyl ether MOBDE-5002S-0.2X
6-MeO-BDE-087 6-Methoxy-2,2',3,4,5'-pentabromodiphenyl ether MOBDE-5003S-0.2X
6-MeO-BDE-082 6-Methoxy-2,2',3,3',4-pentabromodiphenyl ether MOBDE-5005S-0.2X
6'-MeO-BDE-099 6'-Methoxy-2,2',4,4',5-pentabromodiphenyl ether MOBDE-5006S-0.2X
5'-MeO-BDE-099 5'-Methoxy-2,2',4,4',5-pentabromodiphenyl ether MOBDE-5007S-0.2X
3-MeO-BDE-100 3-Methoxy-2,2',4,4',6-pentabromodiphenyl ether MOBDE-5008S
4'-MeO-BDE-101 4'-Methoxy-2,2',4,5,5'-pentabromodiphenyl ether MOBDE-5009S
2-MeO-BDE-123 2-Methoxy-2',3,4,4',5-pentabromodiphenyl ether MOBDE-5011S
6-MeO-BDE-157 6-Methoxy-2,3,3',4,4',5'-hexabromodiphenyl ether MOBDE-6001S-0.2X
6-MeO-BDE-140 6-Methoxy-2,2',3,4,4',6'-hexabromodiphenyl ether MOBDE-6002S-0.2X
3-MeO-BDE-154 3-Methoxy-2,2',4,4',5',6-hexabromodiphenyl ether MOBDE-6003S-0.2X
6-MeO-BDE-137 6-Methoxy-2,2',3,4,4',5-hexabromodiphenyl ether MOBDE-6004S-0.2X
3'-MeO-BDE-154 3'-Methoxy-2,2',4,4',5,6-hexabromodiphenyl ether MOBDE-6005S
4-MeO-BDE-187 4-Methoxy-2,2',3,4',5,5',6-heptabromodiphenyl ether MOBDE-7001S
6-MeO-BDE-180 6-Methoxy-2,2',3,4,4',5,5'-heptabromodiphenyl ether MOBDE-7002S
4-MeO-BDE-188 4-Methoxy-2,2',3,4',5,6,6'-heptabromodiphenyl ether MOBDE-7003S
6-MeO-BDE-182 6-Methoxy-2,2',3,4,4',5,6'-heptabromodiphenyl ether MOBDE-7004S-0.2X
4'-MeO-BDE-201 4'-Methoxy-2,2',3,3',4,5',6,6'-heptabromodiphenyl ether MOBDE-8001S
     
Fluorinated PBDEs (Internal Standard) - Expanded to 30
Alternatives for isotopically labeled materials
Some research suggests that a fluorine derivatives of the PBDE parent compound could be used as an internal standard for PBDE analysis, replacing the more costly 13C labeled PBDEs currently used. In addition, FBDEs can be used for ECD (Electron Capture Detection) analysis where the more expensive 13C labeled PBDEs cannot. Experimental testing also suggests that the use of FBDEs as internal standards show improved precision in PBDE analysis. AccuStandard has synthesized the following FBDEs for use as internal standards and has committed to adding to this list based on requests from analytical chemists:
 
Compound (Short Form)    
Qty./Conc. Matrix Cat. No.
4'-Fluoro-4-bromodiphenyl ether New
(F-BDE-003)		 25 µg/mL Isooctane FBDE-2001S-0.5X
50 µg/mL Isooctane FBDE-2001S
3'-Fluoro-2,4-dibromodiphenyl ether
(F-BDE-007)		 25 µg/mL Isooctane FBDE-2001S-0.5X
50 µg/mL Isooctane FBDE-2001S
3'-Fluoro-3,4-dibromodiphenyl ether
(F-BDE-012)		 25 µg/mL Isooctane FBDE-2002S-0.5X
50 µg/mL Isooctane FBDE-2002S
2-Fluoro-4,4'-dibromodiphenyl ether New
(F-BDE-015)		 25 µg/mL Isooctane FBDE-2003S-0.5X
50 µg/mL Isooctane FBDE-2003S
4'-Fluoro-2,3',4-tribromodiphenyl ether
(F-BDE-025)		 25 µg/mL Isooctane FBDE-3001S-0.5X
50 µg/mL Isooctane FBDE-3001S
4'-Fluoro-2,3',6-tribromodiphenyl ether
(F-BDE-027)		 25 µg/mL Isooctane FBDE-3002S-0.5X
50 µg/mL Isooctane FBDE-3002S
2'-Fluoro-2,4,4'-tribromodiphenyl ether
(F-BDE-028)		 25 µg/mL Isooctane FBDE-3003S-0.5X
50 µg/mL Isooctane FBDE-3003S
3'-Fluoro-2,4,4'-tribromodiphenyl ether
(F-BDE-028)		 25 µg/mL Isooctane FBDE-3004S-0.5X
50 µg/mL Isooctane FBDE-3004S
4'-Fluoro-2,3',4,6-tetrabromodiphenyl ether
(F-BDE-069)		 25 µg/mL Isooctane FBDE-4001S-0.5X
50 µg/mL Isooctane FBDE-4001S
4'-Fluoro-2,3',4,5-tetrabromodiphenyl ether
(F-BDE-067)		 25 µg/mL Isooctane FBDE-4002S-0.5X
50 µg/mL Isooctane FBDE-4002S
6-Fluoro-2,2',4,4'-tetrabromodiphenyl ether
(F-BDE-047)		 25 µg/mL Isooctane FBDE-4003S-0.5X
50 µg/mL Isooctane FBDE-4003S
6-Fluoro-2,3',4,4'-tetrabromodiphenyl ether
(F-BDE-066)		 25 µg/mL Isooctane FBDE-4004S-0.5X
50 µg/mL Isooctane FBDE-4004S
5,5'-Difluoro-2,2',4,4'-tetrabromodiphenyl ether
(F-BDE-047)		 25 µg/mL Isooctane FBDE-4005S-0.5X
50 µg/mL Isooctane FBDE-4005S
3-Fluoro-2,3',4',5-tetrabromodiphenyl ether New
(F-BDE-070)		 25 µg/mL Isooctane FBDE-4006S-0.5X
50 µg/mL Isooctane FBDE-4006S
5-Fluoro-3,3',4,4'-tetrabromodiphenyl ether New
(F-BDE-077)		 25 µg/mL Isooctane FBDE-4007S-0.5X
50 µg/mL Isooctane FBDE-4007S
6'-Fluoro-2,2',4,4',5-pentabromodiphenyl ether New
(F-BDE-099)		 25 µg/mL Isooctane FBDE-5001S-0.5X
50 µg/mL Isooctane FBDE-5001S
3-Fluoro-2,2',4,4',6-pentabromodiphenyl ether
(F-BDE-100)		 25 µg/mL Isooctane FBDE-5002S-0.5X
50 µg/mL Isooctane FBDE-5002S
3,6-Difluoro-2,2',4,4',5-pentabromodiphenyl ether
(2F-BDE-099)		 25 µg/mL Isooctane FBDE-5003S-0.5X
50 µg/mL Isooctane FBDE-5003S
5,6-Difluoro-2,2',3,4,4'-pentabromodiphenyl ether
(2F-BDE-085)		 25 µg/mL Isooctane FBDE-5004S-0.5X
50 µg/mL Isooctane FBDE-5004S
3,5-Difluoro-2,3',4,4',6-pentabromodiphenyl ether
(2F-BDE-119)		 25 µg/mL Isooctane FBDE-5005S-0.5X
50 µg/mL Isooctane FBDE-5005S
3'-Fluoro-2',3,4,5,5'-pentabromodiphenyl ether New
(F-BDE-124)		 25 µg/mL Isooctane FBDE-5006S-0.5X
50 µg/mL Isooctane FBDE-5006S
5'-Fluoro-2',3,4,5,5'-pentabromodiphenyl ether New
(F-BDE-118)		 25 µg/mL Isooctane FBDE-5007S-0.5X
50 µg/mL Isooctane FBDE-5007S
5'-Fluoro-2,3',4,4',5-pentabromodiphenyl ether New
(F-BDE-126)		 25 µg/mL Isooctane FBDE-5008S-0.5X
50 µg/mL Isooctane FBDE-5008S
4'-Fluoro-2,3,3',4,5,6-hexabromodiphenyl ether
(F-BDE-160)		 25 µg/mL Isooctane FBDE-6001S-0.5X
50 µg/mL Isooctane FBDE-6001S
3-Fluoro-2,2',4,4',5,6-hexabromodiphenyl ether
(F-BDE-139)		 25 µg/mL Isooctane FBDE-6002S-0.5X
50 µg/mL Isooctane FBDE-6002S
3-Fluoro-2,2',4,4',5,5'-hexabromodiphenyl ether New
(F-BDE-153)		 25 µg/mL Isooctane FBDE-6003S-0.5X
50 µg/mL Isooctane FBDE-6003S
3'-Fluoro-2,2',4,4',5,6'--hexabromodiphenyl ether New
(F-BDE-154)		 25 µg/mL Isooctane FBDE-6004S-0.5X
50 µg/mL Isooctane FBDE-6004S
3-Fluoro-2,2',4,4',5,5',6-heptabromodiphenyl ether New
(F-BDE-183)		 25 µg/mL Isooctane FBDE-7001S-0.5X
       
4',6-Difluoro-2,2',3,3',4,5,5',6'-octabromodiphenyl ether
(2F-BDE-201)		 25 µg/mL Isooctane FBDE-8001S-0.5X
50 µg/mL Isooctane FBDE-8001S
4'-Fluoro-2,2',3,3',4,5,5',6,6'-nonabromodiphenyl ether
(F-BDE-208)		 25 µg/mL Isooctane FBDE-9001S-0.5X
50 µg/mL Isooctane FBDE-9001S
         
NEW Mixed Bromo/Chloro Hydroxylated Diphenyl Ethers
The abundance of PBDEs in the environment led to the increased detection of hydroxylated PBDEs (OH-PBDEs) as well as their chlorinated derivatives (OH-PBCDEs) especially in aquatic environments. Several pathways of their formation have been described in the literature. In saltwater systems, some of the OH-PBDEs are being produced naturally; while in freshwater systems, atmospheric and wastewater treatment oxidation seems to be the major source of these compounds. Furthermore, disinfection with chlorine of wastewater may lead to the chlorination of OH-PBDEs. These mixed bromo/chloro hydroxy diphenyl ethers (OH-PBCDEs) can then undergo photochemical cyclization in the presence of sunlight to form the potentially even more harmful brominated/chlorinated dibenzo-p-dioxins (Br/Cl-DDs). There is growing concern that both naturally and anthropogenically produced PBDDs and Br/Cl-DDs are an emerging environmental problem.

At AccuStandard, following the lead of environmental chemists, we recognize the emerging problem of the presence of OH-PBCDEs. We have synthesized three OH-PBCDEs and their methylated counterparts to provide reference standards for this new group of compounds. All three chlorinated OH-PBDEs are based on the structure of BDE-47, the most common BDE congener found in environmental samples.
 
AccuStandard, Inc. will synthesize more derivatives as demand for these compounds develops.
Compound (Short Form)    
Qty./Conc. Matrix Cat. No.
Hydroxy        
3-Chloro-6-hydroxy-2,2',4,4'-tetrabromodiphenyl ether
(3-Cl-6-OH-BDE-047)		 25 µg/mL AcCN HCBDE-4001S-0.5X
50 µg/mL AcCN HCBDE-4001S
3,5-Dichloro-6-hydroxy-2,2',4,4'-tetrabromodiphenyl ether
(3,5-Cl2-6-OH-BDE-047)		 25 µg/mL AcCN HCBDE-4002S-0.5X
50 µg/mL AcCN HCBDE-4002S
5-Chloro-6-hydroxy-2,2',4,4'-tetrabromodiphenyl ether
(5-Cl-6-OH-BDE-047)		 25 µg/mL AcCN HCBDE-4003S-0.5X
50 µg/mL AcCN HCBDE-4003S
         
Methoxy        
3-Chloro-6-methoxy-2,2',4,4'-tetrabromodiphenyl ether
(3-Cl-6-MeO-BDE-047)		 25 µg/mL MeOH MOCBDE-4001S-0.5X
50 µg/mL MeOH MOCBDE-4001S
3,5-Dichloro-6-methoxy-2,2',4,4'-tetrabromodiphenyl ether (3,5-Cl2-6-MeO-BDE-047) 25 µg/mL MeOH MOCBDE-4002S-0.5X
50 µg/mL MeOH MOCBDE-4002S

5-Chloro-6-methoxy-2,2',4,4'-tetrabromodiphenyl ether
(5-Cl-6-MeO-BDE-047)

 25 µg/mL MeOH MOCBDE-4003S-0.5X
50 µg/mL MeOH MOCBDE-4003S
         
HBCD Isomers
 
Hexabromocyclododecane (HBCD) Isomers
100 µg/mL each in Toluene
 
.
a-Hexabromocyclododecane HXBCD-01
b-Hexabromocyclododecane HXBCD-02
g-Hexabromocyclododecane HXBCD-03
   
Bromobiphenyl Congeners
 
Compound    
Qty./Conc. Matrix Cat. No.
2-Bromobiphenyl 50 mg NEAT B-001N
35 µg/mL Isooctane B-001S
1 mg/mL Acetone M-8081-SS-X
3-Bromobiphenyl 50 mg NEAT B-002N
35 µg/mL Isooctane B-002S
4-Bromobiphenyl 50 mg NEAT B-003N
35 µg/mL Isooctane B-003S
2,2’-Dibromobiphenyl 10 mg NEAT B-004N
35 µg/mL Isooctane B-004S
2,4-Dibromobiphenyl 10 mg NEAT B-007N-10MG
35 µg/mL Isooctane B-007S
2,5-Dibromobiphenyl 25 mg NEAT B-009N
35 µg/mL Isooctane B-009S
2,6-Dibromobiphenyl 5 mg NEAT B-010N-5MG
35 µg/mL Isooctane B-010S
4,4’-Dibromobiphenyl 10 mg NEAT B-015N
35 µg/mL Isooctane B-015S
2,2’,5-Tribromobiphenyl 10 mg NEAT B-018N
35 µg/mL Isooctane B-018S
2,3’,5-Tribromobiphenyl 10 mg NEAT B-026N
35 µg/mL Isooctane B-026S
2,4,5-Tribromobiphenyl 35 µg/mL Isooctane B-029S
2,4,6-Tribromobiphenyl 25 mg NEAT B-030N
35 µg/mL Isooctane B-030S
2,4’,5-Tribromobiphenyl 10 mg NEAT B-031N
35 µg/mL Isooctane B-031S
2,2’,4,5’-Tetrabromobiphenyl 5 mg NEAT B-049N-5MG
35 µg/mL Isooctane B-049S
2,2’,5,5’-Tetrabromobiphenyl 10 mg NEAT B-052N
35 µg/mL Isooctane B-052S
2,2’,5,6’-Tetrabromobiphenyl 5 mg NEAT B-053N-5MG
35 µg/mL Isooctane B-053S
3,3’,4,4’-Tetrabromobiphenyl 35 µg/mL Isooctane B-077S
3,3’,5,5’-Tetrabromobiphenyl 35 µg/mL Isooctane B-080S
2,2',4,5,5'-Pentabromobiphenyl 10 mg NEAT B-101N
35 µg/mL Isooctane B-101S
2,2',4,5',6-Pentabromobiphenyl 10 mg NEAT B-103N
35 µg/mL Isooctane B-103S
2,2’,4,4’,5,5’-Hexabromobiphenyl 35 µg/mL Isooctane B-153S
2,2’,4,4’,6,6’-Hexabromobiphenyl 5 mg NEAT B-155N
35 µg/mL Isooctane B-155S
3,3’,4,4’,5,5’-Hexabromobiphenyl 35 µg/mL Isooctane B-169S
2,2',3,3’,4,5’,6,6'-Octabromobiphenyl 35 µg/mL Isooctane B-200S
Decabromobiphenyl 25 mg NEAT B-209N
35 µg/mL Isooctane B-209S
         
Bromophenols and their Methyl Ethers
 
Bromophenols     Bromoanisoles (Bromophenol methyl ethers)
100 µg/mL in Toluene Cat. No.   50 µg/mL in Methanol Cat. No.
3-Bromophenol BP-003S   2-Bromoanisole BAN-01
4-Bromophenol BP-004S   3-Bromoanisole BAN-02
2,3-Dibromophenol BP-023S   4-Bromoanisole BAN-03
2,4-Dibromophenol BP-024S   2,3-Dibromoanisole BAN-04
2,5-Dibromophenol BP-025S   2,4-Dibromoanisole BAN-05
2,6-Dibromophenol BP-026S   2,5-Dibromoanisole BAN-06
2,3,4-Tribromophenol BP-234S   2,6-Dibromoanisole BAN-07
2,3,6-Tribromophenol New BP-236S   3,5-Dibromoanisole BAN-08
3,5-Dibromophenol BP-035S   2,4,5-Tribromoanisole BAN-09
2,4,5-Tribromophenol BP-245S   2,4,6-Tribromoanisole BAN-10
2,4,6-Tribromophenol BP-246S    
3,4,5-Tribromophenol BP-345S      
2,3,4,5-Tetrabromophenol BP-2345S      
2,3,4,6-Tetrabromophenol BP-2346S      
2,3,5,6-Tetrabromophenol BP-2356S      
Pentabromophenol BP-23456S      
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Industrial Flame Retardants
 
Bromine Containing Industrial Flame Retardants
BFRs		    
Qty./Conc. Matrix Cat. No.
Tetrabromobisphenol A diallyl ether 10 mg NEAT FRS-045N
100 µg/mL Toluene FRS-045S
Hexabromobenzene 10 mg NEAT HA-07N
100 µg/mL Toluene HA-07S
Pentabromotoluene 50 mg NEAT FRS-018N
100 µg/mL Toluene FRS-018S
Pentabromoethylbenzene 100 µg/mL Toluene FRS-048S
2,4,6-Tribromophenyl allyl ether 10 mg NEAT FRS-043N
100 µg/mL Toluene FRS-043S
2,4,6-Tribromophenol 10 mg NEAT BP-246N
100 µg/mL Toluene BP-246S
Decabromodiphenylethane 10 mg NEAT FRS-036N
100 µg/mL Toluene FRS-036S
1,2-bis(2,4,6-Tribromophenxy)ethane 10 mg NEAT FRS-037N
100 µg/mL Toluene FRS-037S
1,4-bis(Pentabromophenoxy)tetrabromobenzene 10 mg NEAT FRS-052N
100 µg/mL Toluene FRS-052S
2,4,6-tris(2,4,6-Tribromophenoxy)-1,3,5-triazine 100 µg/mL Toluene FRS-049S
3-Bromostyrene 10 mg NEAT FRS-050N
100 µg/mL Toluene FRS-050S
4-Bromostyrene 10 mg NEAT FRS-051N
100 µg/mL Toluene FRS-051S
Pentabromobenzyl acrylate 10 mg NEAT FRS-035N
100 µg/mL Toluene FRS-035S
Ethylene bis(tetrabromophthalimide) 10 mg NEAT FRS-053N
100 µg/mL Toluene FRS-053S
Tetrabromophthalic anhydride 10 mg NEAT FRS-007N
100 µg/mL Toluene FRS-007S
bis(2-Ethylhexyl)tetrabromophthalate 10 mg NEAT FRS-040N
100 µg/mL Toluene FRS-040S
1,2-Benzenedicarbixylic acid, 3,4,5,6-tetrabromo-2-(2-hydroxyethoxy)ethyl-2-hydroxypropylester 100 µg/mL Toluene FRS-054S
       
Dibromoneopentyl glycol 10 mg NEAT FRS-011N
100 µg/mL Toluene FRS-011S
Tribomoneopentyl alcohol 10 mg NEAT FRS-046N
100 µg/mL Toluene FRS-046S
tris(Tribromoneopentyl)phosphate 10 mg NEAT FRS-047N
100 µg/mL Toluene FRS-047S
Ammoniumbromide 10 mg NEAT FRS-055N
100 µg/mL Methanol FRS-055S-M
         

Bromine Containing Industrial Flame Retardants (BFRs)
Commercial Grade BFRs

    
Qty./Conc. Matrix Cat. No.
Bromkal™ DE-70-5 50 µg/mL Isooctane BDE-705
Bromkal™ DE-71 50 µg/mL Isooctane BDE-710
Bromkal™ DE-73-6 50 µg/mL Isooctane BDE-736
Bromkal™ DE-79-8 50 µg/mL Isooctane BDE-798
Dow FR-250 100 µg/mL Isooctane B-250S
35 µg/mL Isooctane B-250S-0.35X
Firemaster™ BP4A 10 mg NEAT FRS-006N
100 µg/mL Toluene FRS-006S
Firemaster™ BP-6 100 µg/mL Isooctane B-600S
35 µg/mL Isooctane B-600S-0.35X
Firemaster™ PHT4 10 mg NEAT FRS-007N
100 µg/mL Toluene FRS-007S
Firemaster™ T23P (Michigan Chemical) 10 mg NEAT FRS-008N
100 µg/mL Toluene FRS-008S
Firemaster™ 680 (Great Lakes) 50 mg NEAT FRS-037N
100 µg/mL Toluene FRS-037S
Firemaster 2100™ (Great Lakes) 50 mg NEAT FRS-036N
FR-300BA 10 mg NEAT FRS-009N
100 µg/mL Toluene FRS-009S
FR-651A (Dow) 10 mg NEAT FRS-010N
100 µg/mL Toluene FRS-010S
FR-1138 (Dow) 10 mg NEAT FRS-011N
100 µg/mL Toluene FRS-011S
HBCD SP-75C (Great Lakes) 10 mg NEAT FRS-028N
100 µg/mL Toluene FRS-028S
Hexabromobenzene (Michigan Chemical) 10 mg NEAT FRS-012N
100 µg/mL Toluene FRS-012S
Hexabromobenzene (White Chemical) 10 mg NEAT FRS-013N
100 µg/mL Toluene FRS-013S
Pentabromobenzylacrylate (Tech grade) 10 mg NEAT FRS-035N
100 µg/mL Toluene FRS-035S
Pentabromobenzylbromide (Tech grade) 10 mg NEAT FRS-030N
100 µg/mL Toluene FRS-030S
Pentabromotoluene 10 mg NEAT FRS-018N
100 µg/mL Toluene FRS-018S
Tetrabromo-o-chlorotoluene 10 mg NEAT FRS-021N
100 µg/mL Toluene FRS-021S
TP-69 (Great Lakes) 10 mg NEAT FRS-023N
100 µg/mL Toluene FRS-023S
         

Bromine Containing Industrial Flame Retardants (BFRs)
Other BFRs (Pure)

    
Qty./Conc. Matrix Cat. No.
bis(2-Ethylhexyl)tetrabromophthalate 50 mg NEAT FRS-040N
100 µg/mL Toluene FRS-040S
2-Ethylhexyl-2,3,4,5-tetrabromobenzoate 10 mg NEAT FRS-041N
100 µg/mL Toluene FRS-041S
Hexachlorocyclopantadienyl-dibromocyclooctane 10 mg NEAT FRS-039N
100 µg/mL Toluene FRS-039S
Pentabromobenzylacrylate 10 mg NEAT FRS-035N
100 µg/mL Toluene FRS-035S
Pentabromobenzylbromide 10 mg NEAT FRS-030N
100 µg/mL Toluene FRS-030S
1,2-Dibromo-4-(1,2-dibromoethyl)cyclohexane 10 mg NEAT FRS-038N
100 µg/mL Toluene FRS-038S
(2,3-Dibromopropyl)(2,4,6-tribomophenyl)ether (DPTE) 10 mg NEAT FRS-044N
100 µg/mL Toluene FRS-044S
tris(2,3-Dibromopropyl)isocyanurate 10 mg NEAT FRS-042N
100 µg/mL Toluene FRS-042S
Hexabromobenzene (hydroxyethyl ether) 10 mg NEAT FRS-032N
100 µg/mL Toluene FRS-032S
         
Chlorine Containing Industrial Flame Retardants (CFRs)
CFCs		    
Qty./Conc. Matrix Cat. No.
Chlorafin™ 40 10 mg NEAT FRS-002N
100 µg/mL Toluene FRS-002S
Chlorendic anhydride 10 mg NEAT FRS-001N
100 µg/mL Toluene FRS-001S
bis(2-Chloroethyl)ether 100 µg/mL MeOH APP-9-027
5 mg/mL MeOH AS-E0016
4-Chlorophenyl phenyl ether 100 µg/mL MeOH APP-9-047
5 mg/mL MeOH AS-E0038
Chlorowax™ 500C 10 mg NEAT FRS-004N
100 µg/mL Toluene FRS-004S
Diable 700X 10 mg NEAT FRS-005N
100 µg/mL Toluene FRS-005S
Dechlorane Plus 10 mg NEAT FRS-033N
100 µg/mL Toluene FRS-033S
Hexachlorobutadiene 10 mg NEAT FRS-017N
100 µg/mL Toluene FRS-017S
Paroil™ 179-HV 10 mg NEAT FRS-015N
100 µg/mL Toluene FRS-015S
Paroil™ 170-8 10 mg NEAT FRS-016N
100 µg/mL Toluene FRS-016S
Phosgard™ C 22-R 10 mg NEAT FRS-019N
100 µg/mL Toluene FRS-019S
Phosgard™ 2XC-20 10 mg NEAT FRS-020N
100 µg/mL Toluene FRS-020S
Tetrachlorobisphenol A 10 mg NEAT FRS-022N
100 µg/mL Toluene FRS-022S
Unichlor™ 40-90 10 mg NEAT FRS-024N
100 µg/mL Toluene FRS-024S
Unichlor™ 502-50 10 mg NEAT FRS-025N
100 µg/mL Toluene FRS-025S
Unichlor™ 70AX 10 mg NEAT FRS-026N
100 µg/mL Toluene FRS-026S
         
     
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NEW Organophosphate Flame Retardants (OP-FRs)

Organophosphate compounds (OPs) are high production volume chemicals. They are utilized as flame retardants and plasticizers, antifoaming agents and additives not only in plastics, but in paints, lubricants and hydraulic fluids as well. The chlorinated OP compounds like tris(2-Chloroethyl) phosphate and tris(1,3-Dichloro-2-propyl) phosphate are flame retardants used in both flexible and rigid polyurethane foam (e.g. furniture foam, thermal insulation), rubber, textile coatings, and home electronics. OPs have been detected in indoor air and house dust, surface, ground, and even drinking water. Ongoing toxicological studies have shown several toxic effects of these compounds, prompting the recognition of potential ecological and human health concerns of neurotoxin and carcinogenic nature.

AccuStandard, Inc. is now providing some of the more widely used OP-FRs as reference standards.
           
Compound Other Names Qty. / Conc. Matrix Cat. No.
tris(2-Chloropropyl)phosphate tris(beta-Chloropropyl)phosphate 10 mg NEAT FRS-056N
50 µg/mL Toluene FRS-056S
tris(2,3-Cibromopropyl)phosphate TBPP 10 mg NEAT FRS-057N
50 µg/mL Toluene FRS-057S
tris(2-Chloroethyl)phosphate   10 mg NEAT FRS-058N
50 µg/mL Toluene FRS-058S
tris(1,3-Dichloro-2-propyl)phosphate

TDCP, TDCPP

 10 mg NEAT FRS-059N
50 µg/mL Toluene FRS-059S
tris(1-Chloro-2-propyl)phosphate tris(2-Chloroisopropyl)phosphate 50 µg/mL Toluene FRS-060S
       
           


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